2024

Vol.31 No.3

Editorial Office

Review

  • Journal of the Microelectronics and Packaging Society
  • Volume 31(2); 2024
  • Article

Review

Journal of the Microelectronics and Packaging Society 2024;31(2):9-15. Published online: Jul, 25, 2024

Effect of the Residual Impurity on the Prepreg Surface on the Wettability of Encapsulant for Chip on Board Package

  • Gahui Kim1 , Doheon Kim2 , Kirak Son3 , and Young-Bae Park1,†
    1 School of Materials Science and Engineering, Andong National University, 1375, Gyeongdong-ro, Andong-si, Gyeongsangbuk-do 36729, Korea, 2 Amkor Technology Korea Inc., 150, Songdomirae-ro, Yeonsu-gu, Incheon 21991, Korea, 3 STATS ChipPAC Korea Ltd, 191, Jayumuyeok-ro, Jung-gu, Incheon 22379, Korea
Corresponding author E-mail: ybpark@anu.ac.kr
Abstract

The effect of the residual impurity on the prepreg surface on the wettability of encapsulant for chip on board package was analyzed with microstructure, compositions and chemical bonds using a scanning electron microscope and X-ray photoelectron spectroscopy. As a result, the contact angle of w/ residual impurity sample was measured to be 28° higher than that of w/o residual impurity sample, and the C-O bond was decreased to be 4% lower than that of w/o residual impurity sample. The surface energy of the prepreg decreased because the impurity ions, Na and F, generated by the manufacturing process and wet etching, reacted chemically with the C on the prepreg surface, forming C-F bonds and breaking the C-O bonds on the prepreg surface. Therefore, the wettability of the encapsulant was degraded because the contact angle between the encapsulant and the prepreg was increased.

Keywords Prepreg, Encapsulant, Surface energy, Wettability, Contact angle

REFERENCES
  • S. E. Kim, “Heterogeneous Device Packaging Technology for the Internet of Things Applications(in Kor.)”, J. Microelectron. Packag. Soc., 23(3), 1 (2016).
  • Y. -J. Park, G. -J. Jeong, and K. -S. Kim, “Research Trends in Thermal Interface Materials for Flexible and Stretchable Electronic Device (in Kor.)”, J. Microelectron. Packag. Soc., 31(1), 7 (2024).
  • M. J. Kim, J. A. Heo, J. H. Hyun, and S. -Y. Lee, “Reliability of Cu Interconnect under Compressive Fatigue Deformation Varying Interfacial Adhesion Treatment (in Kor.)”, J. Microelectron. Packag. Soc., 30(4), 105 (2023).
  • K. Son, G. Kim, and Y. B. Park, “Effects of Dielectric Curing Temperature and T/H Treatment on the Interfacial Adhesion Energies of Ti/PBO for Cu RDL Applications of FOWLP (in Kor.)”, J. Microelectron. Packag. Soc., 30(2), 52 (2023).
  • J. -K. Kim, K. Son, and Y. -B. Park, “Interfacial Adhesion and Reliability between Epoxy Resin and Polyimide for Flexible Printed Circuit Board(in Kor.)”, J. Microelectron. Packag. Soc., 24(1), 75 (2017).
  • B. J. Shim, Y. Choi, and J. S. Yi, “Improvement of COF Bending-induced Lead Broken Failure in LCD Module(in Kor.)”, J. KIEEME 21, 265 (2008).
  • B. -J. Kim, M. H. Jeong, S. H. Hwang, H. Y. Lee, S. W. Lee, K. D. Chun, Y. -B. Park, and Y. C. Joo, “Relationship between Tensile Characteristics and Failure by Folding or Bending in Cu Foil on Flexible Substrate(in Kor.)”, J. Microelectron. Packag. Soc., 18(1), 55 (2011).
  • J. -Y. Kim, “Development of an Automatic Test System for Chip on Boards(in Kor.)”, J. Industrial Technology Institute, 18, 237 (2003).
  • H. J. Kim, K. H. Ahn, S. J. Oh, D. H. Kim, J. S. Kim, E. S. Kim, and T. -S. Kim, “Measurement of EMC/PCB Interfacial Adhesion Energy of Chip Package Considering Warpage(in Kor.)”, J. Microelectron. Packag. Soc., 26(4), 101 (2019).
  • F. Steiner, K. Rendl, and V. Wirth, “Correlation Analysis of Wettability Intermetallic Compound Formation and PCB Contamination”, Circuit World, 41(2), 70 (2015).
  • K. J. Min, S. C. Park, K. W. Lee, J. D. Kim, D. G. Kim, G. H. Lee, and Y. -B. Park, “Effect of Ion-beam Pre-treatment of the Interfacial Adhesion of Sputter-deposited Cu film on FR-4 Substrate(in Kor.)”, J. Inst. Met. & Mater., 47(1), 26 (2009).
  • O. -W. Kweon and Y. Jee, “The Development of a Multichip COB Memory Package”, Proc. 6th International Conference on Consumer Electronics (ICCE), Korea, 419, IEIE (1994).
  • B. Wunderle, K. Becker, R. Sinning, O. Wittler, R. Schacht, H. Walter, R. Schneider, K. Halser, N. Simper, B. Michel, and H. Reichl, “Thermo-Mechanical Reliability during Technology Development of Power Chip-on-board Assemblies with Encapsulation”, J. Microsyst. Technol., 15, 1467 (2009).
  • J. J. Kim, H. Y. Kim, B. Y. Bae, S. H. Jung, and S. R. Jung, “Manufacturing Method of Prepreg (in Kor.)”, (2012). Patent No. 10-2010-0140765. Seoul : Kor. Hyosung.
  • M. S. Seo, “Package and Test to increase Semiconductor added Value”, 212-216, Hanol, Seoul (2020).
  • B. I. Noh, C. S. Seok, W. C. Moon, and S. B. Jung, “Effect of Plasma Treatment on Adhesion Characteristics at Interfaces between Underfill and Substrate”, Int. J. Adhes. Adhes., 27(3), 200 (2007).
  • Y. X. Liu, E. T. Kang, K. G. Neoh, J. F. Zhang, C. Q. Cui, and T. B. Lim, “Surface Graft Copolymerization Enhanced Adhesion of an Epoxy-based Printed Circuit Board Substrate (FR-4) to Copper”, IEEE Trans. Adv. Packag., 22(2), 214 (1999).
  • K. J. Min and Y. -B. Park, “Effect of Desmear Treatment on the Interfacial Bonding Mechanism of Electroless-Plated Cu film on FR-4 Substrate(in Kor.)”, J. Mater. Res., 19(11), 625 (2009).
  • K. K. C. Ho, A. F. Lee, and A. Bismarck, “Fluorination of Carbon fibres in Atmospheric Plasma”, Carbon, 45, 775 (2007).
  • H. Jiang, F. M. Plathe, and A. Z. Panagiotopoulos, “Contact angles from Young’s equation in Molecular Dynamics Simulations”, J. Chem. Phys., 147(8), 084708 (2017).
  • S. W. Park and D. Lee, “Adhesive Joint Strength of Glass/Epoxy Composites Surface treated with Nano-size Carbon Black”, Proc. 17th International Conference on Composite Materials (ICCM), United Kingdom, IEEE (2009).
  • C. J. Van Oss, M. K. Chaudhury, and R. J. Good, “Monopolar Surfaces”, J. Colloid Interf. Sci., 28, 35 (1987).
  • M. H. Kim, K. Y. Rhee, and Y. N. Paik, “Plasma Treatment of Carbon/Epoxy Prepreg and its Effect on the Durability of Carbon/Epoxy Laminated Composites”, J. Kor. Phys. Soc., 54(3), 1325 (2008).
  • K. K. C. Ho, S. Lamoriniere, G. Kalinka, E. Shulz, and A. Bismarck, “Interfacial behavior between Atmospheric Plasma Fluorinated Carbon Fibers and Poly (vinylidene fluoride)”, J. Colloid Interf. Sci., 313, 476 (2007).